If you want Auto Fill in KeePassXC to work in the FFXIV Launcher, make sure Remember ID is turned off and use the following Sequence:
{TAB}{PASSWORD}{ENTER}{USERNAME}{ENTER}
The window title is FFXIVLauncher.
This only works if you don't use a 2fa token, and takes advantage of a weird quirk where pressing Enter on the Password field when the Username field is empty places the cursor focus on the Username field.
I really, really wish that SquareEnix didn't come up with a proprietary 2FA solution. It all but guarantees that I won't use it because I absolutely do not trust them to maintain their proprietary mobile app for it.